N'-[(E)-4-溴-亚苄基]-1-苯并呋喃-2-碳酰肼一水合物
N'-[(E)-4-Bromo-benzyl-idene]-1-benzofuran-2-carbohydrazide monohydrate.
作者信息
Fun Hoong-Kun, Quah Ching Kheng, Kalluraya Balakrishna, Babu M
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):o2121. doi: 10.1107/S1600536812026724. Epub 2012 Jun 16.
Abstract
The title compound, C(16)H(11)BrN(2)O(2)·H(2)O, exists in a trans conformation with respect to the N=C bond [1.2815 (14) Å] and the benzofuran ring system forms a dihedral angle of 2.96 (5)° with the benzene ring. In the crystal, the ketone O atom accepts two O-H⋯O and one C-H⋯O hydrogen bond, and the water O atom accepts an N-H⋯O inter-action. Together, these lead to infinite layers lying parallel to (100).
摘要
标题化合物C(16)H(11)BrN(2)O(2)·H(2)O，相对于N=C键[1.2815 (14) Å]呈反式构象，苯并呋喃环系统与苯环形成2.96 (5)°的二面角。在晶体中，酮O原子接受两个O-H⋯O和一个C-H⋯O氢键，水O原子接受一个N-H⋯O相互作用。这些共同导致平行于(100)的无限层。
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