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(E)-4-甲氧基-N'-[(吡啶-4-基)亚甲基]苯甲酰肼一水合物

(E)-4-Meth-oxy-N'-[(pyridin-4-yl)methyl-idene]benzohydrazide monohydrate.

作者信息

Taha Muhammad, Naz Humera, Rahman Aqilah Abd, Ismail Nor Hadiani, Sammer Yousuf

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):o2778. doi: 10.1107/S1600536812034988. Epub 2012 Aug 25.

Abstract

In the title compound, C(14)H(13)N(3)O(2)·H(2)O, the azomethine double bond adopts an E conformation and the N-N=C-C torsion angle is 178.37 (19)°. The dihedral angle between the benzene and pyridine rings is 5.58 (12)° and the C atom of the meth-oxy group is roughly coplanar with its attached ring [deviation = 0.157 (3) Å]. In the crystal, the components are linked by O-H⋯O, O-H⋯N, N-H⋯O and C-H⋯O hydrogen bonds, forming (001) sheets. The water O atom accepts one N-H⋯O and two C-H⋯O inter-actions from the adjacent organic mol-ecule.

摘要

在标题化合物C₁₄H₁₃N₃O₂·H₂O中,偶氮甲碱双键呈E构型,N-N=C-C扭转角为178.37 (19)°。苯环和吡啶环之间的二面角为5.58 (12)°,甲氧基的C原子与其相连的环大致共面[偏差 = 0.157 (3) Å]。在晶体中,各组分通过O-H⋯O、O-H⋯N、N-H⋯O和C-H⋯O氢键相连,形成(001)层。水分子的O原子接受来自相邻有机分子的一个N-H⋯O和两个C-H⋯O相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6e97/3435810/0546f090148b/e-68-o2778-fig1.jpg

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