Division of Chemistry & Biological Chemistry, School of Physical & Mathematical Sciences, Nanyang Technological University, Singapore 637371.
J Org Chem. 2012 Aug 17;77(16):6849-54. doi: 10.1021/jo300893s. Epub 2012 Aug 9.
A highly reactive, chemo- and enantioselective addition of diphenylphosphine to α,β-unsaturated imines catalyzed by a palladacycle has been developed, thus providing the access to a series of chiral tertiary enaminophosphines in high yields. A putative catalytic cycle has also been proposed.
一种高活性的、对映选择性的钯环催化二苯基膦与α,β-不饱和亚胺的加成反应已被开发出来，从而为一系列手性叔烯基膦的高收率合成提供了途径。还提出了一个可能的催化循环。
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