PhotoGreen Lab, Department of Chemistry, University of Pavia, Viale Taramelli 12, 27100 Pavia, Italy.
Org Lett. 2012 Aug 17;14(16):4218-21. doi: 10.1021/ol301900p. Epub 2012 Aug 2.
Excited tetrabutylammonium decatungstate (TBADT), known to activate a variety of compounds via hydrogen atom transfer (HAT), has now been applied as a photoredox catalyst for the effective oxidative cleavage of benzyl silanes and radical benzylation of reducible olefins occurring in isolated yields from poor to excellent.
四丁基高铼酸盐（TBADT）是一种已知可通过氢原子转移（HAT）激活多种化合物的物质，现已被应用于光氧化还原催化剂，可有效氧化裂解苄基硅烷，并实现可还原烯烃的自由基苄基化，产率从较差到优秀不等。
