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三[2,4-二氯-6-(乙基亚氨基甲基)苯酚根-κ(2)N,O]钴(III)

Tris[2,4-dichloro-6-(ethyl-imino-meth-yl)phenolato-κ(2)N,O]cobalt(III).

作者信息

Huang Qiu Ping, Guo Jing Jing, Zhang Yi Dong, Zhang Shu Hua

机构信息

College of Chemistry and Bioengineering, Guilin University of Technology, Key Laboratory of Non-ferrous Metal Materials and Processing Technology, Ministry of Education, Guilin, 541004, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):m1047. doi: 10.1107/S160053681203067X. Epub 2012 Jul 10.

DOI:10.1107/S160053681203067X
PMID:22904723
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3414116/
Abstract

The asymmetric unit of the title compound, [Co(C(9)H(8)Cl(2)NO)(3)], contains three independent mol-ecules. In each mol-ecule, the Co(III) ion is coordinated by an O atom and an N atom from three bidentate 2,4-dichloro-6-(ethyl-imino-meth-yl)phenolate ligands in a slightly distorted octa-hedral environment. In the crystal, a weak C-H⋯Cl hydrogen bond is observed.

摘要

标题化合物[Co(C₉H₈Cl₂NO)₃]的不对称单元包含三个独立分子。在每个分子中，Co(III)离子由来自三个双齿2,4-二氯-6-(乙基亚氨基甲基)苯酚盐配体的一个O原子和一个N原子配位，处于略微扭曲的八面体环境中。在晶体中，观察到一个弱的C-H⋯Cl氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c8b8/3414116/48595d0a067e/e-68-m1047-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c8b8/3414116/3f5447632f30/e-68-m1047-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c8b8/3414116/7a70bc0a949f/e-68-m1047-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c8b8/3414116/48595d0a067e/e-68-m1047-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c8b8/3414116/3f5447632f30/e-68-m1047-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c8b8/3414116/7a70bc0a949f/e-68-m1047-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c8b8/3414116/48595d0a067e/e-68-m1047-fig3.jpg

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