Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 10691 Stockholm, Sweden.
Chemistry. 2012 Sep 10;18(37):11498-523. doi: 10.1002/chem.201201494. Epub 2012 Aug 22.
Palladium-catalyzed oxidative carbon-carbon bond-forming annulations, that is, carbocyclization reactions, have recently emerged as efficient and atom-economical routes to carbo- and heterocycles, whereby less functionalized substrates and fewer synthetic steps are needed to obtain a target molecule compared with traditional non-oxidative carbon-carbon bond-forming reactions. In this review, the synthetic efforts in palladium-catalyzed oxidative carbocyclization reactions are summarized.
钯催化的氧化碳-碳键形成环化反应，即碳环化反应，最近作为高效和原子经济的方法被应用于碳环和杂环化合物的合成，与传统的非氧化碳-碳键形成反应相比，该方法需要的功能化底物和合成步骤更少，就能得到目标分子。在这篇综述中，总结了钯催化的氧化碳环化反应的合成研究进展。
