Institut Jean Lamour, UMR INC-CNRS - Université de Lorraine, Ecole des Mines, Nancy, France.
Chem Soc Rev. 2012 Oct 21;41(20):6760-77. doi: 10.1039/c2cs35110b. Epub 2012 Aug 29.
This article aims at an account of what is known about the potential for applications of quasicrystals and related compounds, the so-called family of Complex Metallic Alloys (CMAs‡). Attention is focused at aluminium-based CMAs, which comprise a large number of crystalline compounds and quasicrystals made of aluminium alloyed with transition metals (like Fe or Cu) or normal metals like Mg. Depending on composition, the structural complexity varies from a few atoms per unit cell up to thousands of atoms. Quasicrystals appear then as CMAs of ultimate complexity and exhibit a lattice that shows no periodicity anymore in the usual 3-dimensional space. Properties change dramatically with lattice complexity and turn the metal-type behaviour of simple Al-based crystals into a far more complex behaviour, with a fingerprint of semi-conductors that may be exploited in various applications, potential or realised. An account of the ones known to the author is given in the light of the relevant properties, namely light absorption, reduced adhesion and friction, heat insulation, reinforcement of composites for mechanical devices, and few more exotic ones. The role played by the search for applications of quasicrystals in the development of the field is briefly addressed in the concluding section.
本文旨在介绍准晶及其相关化合物(所谓的复杂金属合金(CMA)家族)的潜在应用。关注的焦点是基于铝的 CMA,它由大量由铝合金与过渡金属(如 Fe 或 Cu)或正常金属(如 Mg)制成的晶态化合物和准晶组成。根据成分,结构的复杂性从每个单元晶胞中的几个原子到数千个原子不等。准晶作为最复杂的 CMA 出现,其晶格在通常的三维空间中不再具有周期性。晶格复杂性的变化会导致金属型行为发生剧烈变化,将简单的基于 Al 的晶体的行为转变为更为复杂的行为,具有半导体的特征,这可能在各种潜在或已实现的应用中得到利用。根据作者所了解的相关特性(即光吸收、降低的附着力和摩擦、隔热、机械装置复合材料的增强以及更多奇特的特性),本文介绍了已知的应用。在结论部分简要讨论了准晶应用的研究在该领域发展中的作用。