铜催化烯丙基锆烯与邻苯甲酰基羟胺的亲电胺化反应：合成烯胺的有效方法。
Copper-catalyzed electrophilic amination of alkenylzirconocenes with O-benzoylhydroxylamines: an efficient method for synthesis of enamines.
机构信息
Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, China.
出版信息
Org Lett. 2012 Sep 21;14(18):4750-3. doi: 10.1021/ol302004t. Epub 2012 Sep 6.
PMID:22954174
Abstract
Copper-catalyzed electrophilic amination of alkenylzirconocenes is accomplished under mild reaction conditions. The reaction tolerates a wide range of functional groups and can be used to prepare some hindered enamines.
摘要
铜催化的烯丙基锆烯的亲电胺化反应在温和的反应条件下完成。该反应能耐受广泛的官能团，并可用于制备一些受阻的烯胺。
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