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Copper-mediated amidation of heterocyclic and aromatic C-H bonds.
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Synthesis of 1,2-disubstituted benzimidazoles by a Cu-catalyzed cascade aryl amination/condensation process.
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Microwave-enhanced additive-free C-H amination of benzoxazoles catalysed by supported copper.
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A One-Pot Synthesis-Functionalization Strategy for Streamlined Access to 2,5-Disubstituted 1,3,4-Oxadiazoles from Carboxylic Acids.
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Cross-Coupling of Heteroatomic Electrophiles.
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Cobalt-Catalyzed Electrophilic Aminations with Anthranils: An Expedient Route to Condensed Quinolines.
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Copper-catalyzed diamination of unactivated alkenes with hydroxylamines.
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Photoredox ketone catalysis for the direct C-H imidation and acyloxylation of arenes.
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Site-Selective Copper-Catalyzed Amination and Azidation of Arenes and Heteroarenes via Deprotonative Zincation.
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Ortho vs ipso: site-selective Pd and norbornene-catalyzed arene C-H amination using aryl halides.
J Am Chem Soc. 2013 Dec 11;135(49):18350-3. doi: 10.1021/ja410823e. Epub 2013 Nov 26.
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Regioselective functionalization of the oxazole scaffold using TMP-bases of Mg and Zn.
Org Lett. 2013 Dec 20;15(24):6162-5. doi: 10.1021/ol403019c. Epub 2013 Nov 18.
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Rhodium(III)-catalyzed C-H activation and amidation of arenes using N-arenesulfonated imides as amidating reagents.
Org Lett. 2013 Jul 19;15(14):3706-9. doi: 10.1021/ol401569u. Epub 2013 Jul 3.
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Direct C-H amination of arenes with alkyl azides under rhodium catalysis.
Angew Chem Int Ed Engl. 2013 Jul 29;52(31):8031-6. doi: 10.1002/anie.201302784. Epub 2013 Jun 20.
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Expedient C-H amidations of heteroaryl arenes catalyzed by versatile ruthenium(II) catalysts.
Org Lett. 2013 Jul 5;15(13):3286-9. doi: 10.1021/ol401321q. Epub 2013 Jun 14.
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Rh[III]-catalyzed C-H amidation using aroyloxycarbamates to give N-Boc protected arylamines.
Org Lett. 2013 Jun 21;15(12):3014-7. doi: 10.1021/ol401209f. Epub 2013 May 31.
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Small molecule inhibition of the KRAS-PDEδ interaction impairs oncogenic KRAS signalling.
Nature. 2013 May 30;497(7451):638-42. doi: 10.1038/nature12205. Epub 2013 May 22.
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Directed amination of non-acidic arene C-H bonds by a copper-silver catalytic system.
Angew Chem Int Ed Engl. 2013 Jun 3;52(23):6043-6. doi: 10.1002/anie.201300135. Epub 2013 Apr 24.
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Copper-catalyzed electrophilic amination of arylsilanes with hydroxylamines.
Org Lett. 2013 Jan 4;15(1):172-5. doi: 10.1021/ol303222s. Epub 2012 Dec 20.

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