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(E)-N'-(3,4-二甲氧基-亚苄基)-4-甲氧基-苯甲酰肼

(E)-N'-(3,4-Dimeth-oxy-benzyl-idene)-4-meth-oxy-benzohydrazide.

作者信息

Taha Muhammad, Naz Humera, Rahman Aqilah Abd, Ismail Nor Hadiani, Sammer Yousuf

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):o2780. doi: 10.1107/S1600536812034228. Epub 2012 Aug 25.

Abstract

In the title compound, C(17)H(18)N(2)O(4), the azomethine double bond adopts an E conformation with an N-N-C-C torsion angle of -178.3 (3)°. The benzene rings are almost coplaner, with a dihedral angle of 2.98 (14)° between their mean planes. In the crystal, the molecules are linked by N-H⋯O hydrogen bonds, resulting in chains of mol-ecules lying parallel to the b axis. The structure is further consolidated by rather weak C-H⋯O hydrogen-bonding inter-actions, resulting in six-membered rings about inversion centers linked into chains arranged parallel to the b axis.

摘要

在标题化合物C(17)H(18)N(2)O(4)中,偶氮甲碱双键呈E构象,N-N-C-C扭转角为-178.3 (3)°。苯环几乎共面,其平均平面之间的二面角为2.98 (14)°。在晶体中,分子通过N-H⋯O氢键相连,形成平行于b轴的分子链。结构通过相当弱的C-H⋯O氢键相互作用进一步巩固,形成围绕反演中心的六元环,这些环连接成平行于b轴排列的链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fcee/3435812/fe8af3ae8f6c/e-68-o2780-fig1.jpg

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