可见光光氧化还原催化的α-氨基酸羰基化合物与吲哚的直接α-芳基化反应。
Direct α-arylation of α-amino carbonyl compounds with indoles using visible light photoredox catalysis.
机构信息
State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China.
出版信息
J Org Chem. 2012 Oct 5;77(19):8705-11. doi: 10.1021/jo301691h. Epub 2012 Sep 25.
PMID:22985461
Abstract
A general and mild method for the construction of functionalized 2-(1H-indol-3-yl)-2-amino-carbonyl compounds was achieved, which represents the first example of direct α-arylation of α-amino carbonyl compounds with indoles using the visible light photoredox catalysis strategy.
摘要
实现了一种通用且温和的方法，用于构建功能化的 2-(1H-吲哚-3-基)-2-氨基羰基化合物，这代表了使用可见光光氧化还原催化策略直接对α-氨基羰基化合物进行芳基化的首例实例。
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