Supramolecular Chemistry Laboratory, New Chemistry Unit, Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Jakkur P.O, Bangalore 560064, India.
Chemistry. 2012 Nov 5;18(45):14286-91. doi: 10.1002/chem.201202168. Epub 2012 Oct 2.
Mixing it up! The supramolecular alternate co-assembly of extended π-conjugated donor (D) and acceptor (A) molecules (i.e., oligo(phenylenevinylene) and perylenebisimide, respectively), to 1-D nanotubes with an unprecedented mixed stack D-A molecular structure is presented, through a non-covalent amphiphilic design strategy, which results in the formation of hydrogels with remarkable mechanical properties (see scheme).
混合起来！通过非共价两亲性设计策略，将扩展的π-共轭供体（D）和受体（A）分子（即聚（苯乙烯基）和并苯二酰亚胺，分别）交替共组装到具有前所未有的混合堆叠 D-A 分子结构的 1-D 纳米管中，从而形成具有显著机械性能的水凝胶（见图）。
