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聚合物固载金/钯合金纳米粒子催化醇和胺与分子氧选择性形成亚胺。

Selective imine formation from alcohols and amines catalyzed by polymer incarcerated gold/palladium alloy nanoparticles with molecular oxygen as an oxidant.

机构信息

Department of Chemistry, School of Science, The University of Tokyo, Hongo, Tokyo 113-0033, Japan.

出版信息

Chem Commun (Camb). 2013 Jan 14;49(4):355-7. doi: 10.1039/c2cc36213a. Epub 2012 Oct 5.

DOI:10.1039/c2cc36213a
PMID:23037545
Abstract

Carbon black stabilized, polymer incarcerated gold/palladium alloy nanoparticles (PICB-Au/Pd) act as an efficient, reusable heterogeneous catalyst for imine synthesis from alcohols and amines through a tandem oxidative process using molecular oxygen as the terminal oxidant.

摘要

炭黑稳定、聚合物包埋的金/钯合金纳米粒子(PICB-Au/Pd)作为一种高效、可重复使用的非均相催化剂,可通过使用分子氧作为末端氧化剂的串联氧化过程,从醇和胺合成亚胺。

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