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应用地积累指数和富集因子评估沉积物中的重金属污染。

Application of geoaccumulation index and enrichment factors on the assessment of heavy metal pollution in the sediments.

机构信息

Environmental Forensics Research Centre, Faculty of Environmental Studies, Universiti Putra Malaysia, Selangor, Malaysia.

出版信息

J Environ Sci Health A Tox Hazard Subst Environ Eng. 2013;48(2):182-90. doi: 10.1080/10934529.2012.717810.

DOI:10.1080/10934529.2012.717810
PMID:23043340
Abstract

An investigative study was carried out in Langat River to determine the heavy metal pollution in the sediment with 22 sampling stations selected for the collection of sediment samples. The sediment samples were digested and analyzed for extractable metal ((48)Cd, (29)Cu, (30)Zn, (33)As, (82)Pb) using the Inductively Coupled Plasma-Mass Spectrometry (ICP-MS). Parameters, such as pH, Eh, electrical conductivity (EC), salinity, cation exchange capacity (CEC) and loss on ignition (LOI) were also determined. The assessment of heavy metal pollution was derived using the enrichment factors (EF) and geoaccumulation index (I(geo)). This study revealed that the sediment is predominantly by As > Cd > Pb > Zn > Cu. As recorded the highest EF value at 187.45 followed by Cd (100.59), Pb (20.32), Zn (12.42) and Cu (3.46). This is similar to the I(geo), which indicates that the highest level goes to As (2.2), exhibits moderately polluted. Meanwhile, Cd recorded 1.8 and Pb (0.23), which illustrates that both of these elements vary from unpolluted to moderately polluted. The Cu and Zn levels are below 0, which demonstrates background concentrations. The findings are expected to update the current status of the heavy metal pollution as well as creating awareness concerning the security of the river water as a drinking water source.

摘要

本研究在冷岳河进行了一项调查性研究,以确定沉积物中的重金属污染情况。为此,在 22 个采样点采集了沉积物样本。使用电感耦合等离子体质谱法(ICP-MS)对沉积物样本进行消解和可提取金属((48)Cd、(29)Cu、(30)Zn、(33)As、(82)Pb)分析。还测定了 pH、Eh、电导率 (EC)、盐度、阳离子交换容量 (CEC) 和烧失量 (LOI) 等参数。使用富集因子 (EF) 和地质累积指数 (I(geo)) 来评估重金属污染。本研究表明,沉积物中主要重金属为 As > Cd > Pb > Zn > Cu。As 的 EF 值最高,为 187.45,其次是 Cd(100.59)、Pb(20.32)、Zn(12.42)和 Cu(3.46)。这与 I(geo) 相似,表明 As 的污染程度最高(2.2),属于中度污染。同时,Cd 的污染程度为 1.8,Pb 的污染程度为 0.23,表明这两种元素的污染程度从无污染到中度污染不等。Cu 和 Zn 的含量低于 0,表明它们处于背景浓度水平。本研究结果有望更新重金属污染的现状,并提高人们对河水作为饮用水源安全性的认识。

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