钌亚硝酰配合物作为可调变的烯烃复分解反应和其他转化的催化剂。
Ruthenium nitronate complexes as tunable catalysts for olefin metathesis and other transformations.
机构信息
Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224, Warsaw, Poland.
出版信息
Chem Commun (Camb). 2013 Jan 25;49(7):674-6. doi: 10.1039/c2cc37385h.
PMID:23223376
Abstract
Novel ruthenium(II) complexes were obtained as a result of a stoichiometric reaction of Grubbs' benzylidene second generation catalysts with 3-nitropropene. These stable complexes, formally ruthenaisoxazole N-oxide derivatives, display activity in both metathesis and non-metathetic processes such as cycloisomerisation, isomerisation and transfer hydrogenation.
摘要
新型钌（II）配合物是通过 Grubbs 苄叉第二代催化剂与 3-硝基丙烯的化学计量反应得到的。这些稳定的配合物，形式上是钌异恶唑 N-氧化物衍生物，在复分解和非复分解过程中都具有活性，如环化异构化、异构化和转移氢化。
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