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中国巢湖水体中有机氯农药的残留、分布、来源及生态风险

Residues, distributions, sources, and ecological risks of OCPs in the water from Lake Chaohu, China.

作者信息

Liu Wen-Xiu, He Wei, Qin Ning, Kong Xiang-Zhen, He Qi-Shuang, Ouyang Hui-Ling, Yang Bin, Wang Qing-Mei, Yang Chen, Jiang Yu-Jiao, Wu Wen-Jing, Xu Fu-Liu

机构信息

MOE Laboratory for Earth Surface Processes, College of Urban and Environmental Sciences, Peking University, Beijing 100871, China.

出版信息

ScientificWorldJournal. 2012;2012:897697. doi: 10.1100/2012/897697. Epub 2012 Nov 28.

Abstract

The levels of 18 organochlorine pesticides (OCPs) in the water from Lake Chaohu were measured by a solid phase extraction-gas chromatography-mass spectrometer detector. The spatial and temporal distribution, possible sources, and potential ecological risks of the OCPs were analyzed. The annual mean concentration for the OCPs in Lake Chaohu was 6.99 ng/L. Aldrin, HCHs, and DDTs accounted for large proportions of the OCPs. The spatial pollution followed the order of Central Lakes > Western Lakes > Eastern Lakes and water area. The sources of the HCHs were mainly from the historical usage of lindane. DDTs were degraded under aerobic conditions, and the main sources were from the use of technical DDTs. The ecological risks of 5 OCPs were assessed by the species sensitivity distribution (SSD) method in the order of heptachlor > γ-HCH > p,p'-DDT > aldrin > endrin. The combining risks of all sampling sites were MS > JC > ZM > TX, and those of different species were crustaceans > fish > insects and spiders. Overall, the ecological risks of OCP contaminants on aquatic animals were very low.

摘要

采用固相萃取 - 气相色谱 - 质谱检测器测定了巢湖水体中18种有机氯农药(OCPs)的含量。分析了OCPs的时空分布、可能来源及潜在生态风险。巢湖OCPs的年均浓度为6.99 ng/L。艾氏剂、六氯环己烷(HCHs)和滴滴涕(DDTs)在OCPs中占比很大。空间污染程度顺序为:湖心区>西湖区>东湖区及水域。HCHs的来源主要是林丹的历史使用。DDTs在有氧条件下会降解,其主要来源是工业DDT的使用。采用物种敏感度分布(SSD)方法评估了5种OCPs的生态风险,顺序为:七氯>γ-六氯环己烷>p,p'-滴滴涕>艾氏剂>异狄氏剂。所有采样点的综合风险顺序为:姥山>炯城>中庙>唐嘴,不同物种的综合风险顺序为:甲壳类动物>鱼类>昆虫和蜘蛛。总体而言,OCP污染物对水生动物的生态风险非常低。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5fb4/3515910/d93c4c831c20/TSWJ2012-897697.001.jpg

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