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双{2-溴-4-氯-6-[(E)-(2,6-二甲基苯基)亚氨基甲基]苯酚根合-κ(2)N,O}钴(II)

Bis{2-bromo-4-chloro-6-[(E)-(2,6-di-methyl-phen-yl)imino-meth-yl]phenolato-κ(2) N,O}cobalt(II).

作者信息

Zhu Gang, Jiao Bao-Juan

机构信息

School of Chemistry and Chemical Engineering, Xi'an University of Arts and Science, Xi'an, Shaanxi 710065, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 1;69(Pt 3):m156. doi: 10.1107/S1600536813003747. Epub 2013 Feb 20.

DOI:10.1107/S1600536813003747
PMID:23476501
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3588491/
Abstract

In the title complex, [Co(C15H12BrClNO)2], the Co(II) ion is coordinated by two N,O-bidentate 2-bromo-4-chloro-6-[(E)-(2,6-dimethyl-phen-yl)imino-meth-yl]phenolate ligands, generating a squashed CoN2O2 tetra-hedral coordination geometry. The dihedral angles between the aromatic rings in the ligands are 82.60 (14) and 71.79 (14)°. The complex has approximate local noncrystallographic twofold symmetry. In the crystal, weak aromatic π-π stacking is observed [centroid-centroid separation = 3.6434 (18) Å].

摘要

在标题配合物[Co(C₁₅H₁₂BrClNO)₂]中，Co(II)离子由两个N,O-双齿的2-溴-4-氯-6-[(E)-(2,6-二甲基苯基)亚氨基甲基]苯酚盐配体配位，形成一个压扁的CoN₂O₂四面体配位几何结构。配体中芳环之间的二面角为82.60 (14)°和71.79 (14)°。该配合物具有近似的局部非晶体学二重对称性。在晶体中，观察到弱的芳香π-π堆积作用[质心-质心间距 = 3.6434 (18) Å]。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd9d/3588491/3b766d7e91cb/e-69-0m156-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd9d/3588491/d86be5773330/e-69-0m156-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd9d/3588491/3b766d7e91cb/e-69-0m156-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd9d/3588491/d86be5773330/e-69-0m156-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd9d/3588491/3b766d7e91cb/e-69-0m156-fig2.jpg

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本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
2
Intravenous epoprostenol sodium does not increase hepatic microsomal enzyme activity in rats.
Prostaglandins. 1995 Nov-Dec;50(5-6):341-7. doi: 10.1016/0090-6980(95)00139-5.