Institute of Analytical Chemistry, ASCR, v v i, Brno, Czech Republic.
Lab Chip. 2013 Mar 7;13(5):781-4. doi: 10.1039/c2lc41086a. Epub 2013 Jan 8.
We present a generation of electrochemiluminescence (ECL) signal, based on square shaped gold electrodes with a size of 50 μm positioned inside a fused silica capillary. The ECL was generated using electric pulses with duration in the range from 100 ms to 5 s and an electrical field strength from 300 V cm(-1) to 500 V cm(-1). We have demonstrated that the electrochemical reaction with detectable optical output can be produced using freely moving and thus disposable electrodes.
我们提出了一种基于 50μm 方形金电极的电致化学发光（ECL）信号产生方法，该电极位于熔融石英毛细管内。通过持续时间为 100ms 至 5s 且电场强度为 300V/cm 至 500V/cm 的电脉冲产生 ECL。我们已经证明，使用可自由移动且因此可一次性使用的电极，可以产生具有可检测光学输出的电化学反应。
