Laboratoire de Chimie Physique et Microbiologie pour l'Environnement, UMR 7564 CNRS - Université de Lorraine, 405 rue de Vandoeuvre, 54600 Villers-les-Nancy, France.
Chem Soc Rev. 2013 May 7;42(9):4098-140. doi: 10.1039/c2cs35322a. Epub 2013 Jan 18.
Ordered mesoporous materials prepared by the template route have attracted increasing interest from the electrochemists community due to their plenty of unique properties and functionalities that can be effectively exploited in electrochemical devices. This review will cover the whole field of the intersection between electrochemistry and ordered mesoporous materials. The latter are either electronically insulating (silica and some other metal oxides, as well as silica-based organic-inorganic hybrid materials), semi-conducting (metal oxides), or conducting (metals, carbons). The three main intersection areas are: (1) the development/use of electrochemical methods to characterize the properties of mesoporous materials (i.e., charge and mass transfer processes); (2) the generation of mesostructured solids by electro-assisted deposition using appropriate templates; and (3) the application of these novel materials for electrochemical purposes. The most common devices to date are based on a bulk composite or thin film configuration and the resulting electrodes modified with such mesoporous materials have been successfully applied in various fields, including mainly electrochemical sensing and biosensing as well as energy conversion and storage (620 references).
有序介孔材料通过模板法制备，由于其具有许多独特的性质和功能，可在电化学器件中得到有效利用，因此受到电化学界越来越多的关注。本综述涵盖了电化学和有序介孔材料交叉领域的全部内容。后者要么是电子绝缘的（如二氧化硅和一些其他金属氧化物，以及基于二氧化硅的有机-无机杂化材料），要么是半导体（金属氧化物），要么是导体（金属、碳）。三个主要的交叉领域是：（1）开发/使用电化学方法来表征介孔材料的性质（即电荷和质量转移过程）；（2）通过使用适当的模板进行电辅助沉积来生成介孔结构固体；（3）将这些新型材料应用于电化学目的。迄今为止，最常见的器件基于体复合材料或薄膜结构，并且已经成功地将这些介孔材料修饰的电极应用于各种领域，包括主要的电化学传感和生物传感以及能量转换和存储（620 篇参考文献）。
