一个带有盖帽的[Fe4L4]8+ 自旋交叉四面体笼。
A face-capped [Fe4L4]8+ spin crossover tetrahedral cage.
机构信息
Department of Chemistry, University of Canterbury, Private Bag 4800, Christchurch, 8041, New Zealand.
出版信息
Chem Commun (Camb). 2013 Feb 25;49(16):1597-9. doi: 10.1039/c3cc00012e.
PMID:23334172
Abstract
Reported here is a face-capped Fe(ii) molecular tetrahedron, Fe(4)L(4)(8), . Single crystal X-ray diffraction at 153 and 293 K suggest spin crossover (SCO) and variable temperature magnetic susceptibility measurements confirm displays thermally driven SCO behaviour in the solid state and in dilute acetone solution centred around 284-288 K.
摘要
这里报道的是一个带有面帽的 Fe(ii) 分子四面体 Fe(4)L(4)(8) 。在 153 和 293 K 的单晶 X 射线衍射表明存在自旋交叉（SCO），而变温磁化率测量证实了在固态和稀丙酮溶液中存在以 284-288 K 为中心的热驱动 SCO 行为。
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