Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, Sichuan University, 29 Wangjiang Road, Chengdu 610064, P. R. China.
Org Biomol Chem. 2013 Feb 28;11(8):1290-3. doi: 10.1039/c2ob27325j.
A concise synthetic protocol for aryl functionalized phenanthrolines has been developed. It was demonstrated that 3,8-diphenyl-1,10-phenanthroline (7a) is competent in promoting transition-metal-free direct arylation and 2,3,8,9-tetraphenyl-1,10-phenanthroline (8a) is a highly efficient ligand in the in situ Pd-catalysed Heck reaction.
已经开发出一种芳基功能化菲咯啉的简洁合成方案。结果表明，3,8-二苯基-1,10-菲咯啉（7a）能够有效地促进无过渡金属直接芳基化反应，而 2,3,8,9-四苯基-1,10-菲咯啉（8a）则是原位 Pd 催化 Heck 反应中的高效配体。
