铜催化的烯烃分子间氨氰化和二胺化反应。
Copper-catalyzed intermolecular aminocyanation and diamination of alkenes.
机构信息
Department of Chemistry, Northeast Normal University, Changchun, 130024, China.
出版信息
Angew Chem Int Ed Engl. 2013 Feb 25;52(9):2529-33. doi: 10.1002/anie.201209142. Epub 2013 Jan 25.
PMID:23355412
Abstract
'N' front and center: The facile construction of C-N bonds by the generation of nitrogen-centred radicals from N-fluorobenzenesulfonimide results in the aminative difuctionalization of alkenes. The first copper-catalyzed intermolecular aminocyanation of alkenes and diamination of styrenes were realized. Si-F and B-F interactions play a significant role in the reaction.
摘要
'N' 位于前沿和中心：通过 N-氟代苯磺酰胺产生氮中心自由基，从而轻易地构建 C-N 键，导致烯烃的氨基官能团化。首次实现了铜催化的烯烃的分子间氨氰化和苯乙烯的双氨化反应。Si-F 和 B-F 相互作用在反应中起着重要作用。
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