Dept. Chemical Engineering and Chemistry, Eindhoven University of Technology, STO 1.21, The Netherlands.
Angew Chem Int Ed Engl. 2013 Mar 11;52(11):3074-85. doi: 10.1002/anie.201207548. Epub 2013 Feb 10.
A new generation of designer solvents emerged in the last decade as promising green media for multiple applications, including separation processes: the low-transition-temperature mixtures (LTTMs). They can be prepared by mixing natural high-melting-point starting materials, which form a liquid by hydrogen-bond interactions. Among them, deep-eutectic solvents (DESs) were presented as promising alternatives to conventional ionic liquids (ILs). Some limitations of ILs are overcome by LTTMs, which are cheap and easy to prepare from natural and readily available starting materials, biodegradable, and renewable.
过去十年中出现了新一代的设计溶剂，它们作为有前途的绿色介质，可应用于多种领域，包括分离过程：低共熔混合物（LTTMs）。它们可以通过混合天然高熔点起始原料来制备，这些原料通过氢键相互作用形成液体。其中，深共晶溶剂（DESs）被认为是传统离子液体（ILs）的有前途替代品。LTTMs 克服了 ILs 的一些局限性，它们价格低廉，易于用天然易得的起始原料制备，可生物降解且可再生。
