Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, D-97074, Würzburg, Germany.
Chem Commun (Camb). 2013 Mar 25;49(24):2439-41. doi: 10.1039/c3cc38686d.
A novel μ(2)-bridging coordination mode of the diboran(4)-1,2-diyl ligand was unveiled for dinuclear , in which two Pt(II) centers are connected by the diboran(4)yl moiety. Prolonged heating resulted in the unprecedented reductive elimination of the haloborane from one Pt(II) center to afford mononuclear 2.
揭示了二硼烷（4）-1,2-二基配体的新型 μ(2)-桥联配位模式，用于双核 ，其中两个 Pt(II) 中心通过二硼烷（4）部分连接。延长加热导致卤硼烷从一个 Pt(II) 中心发生前所未有的还原消除，得到单核 2。
