Dipartimento di Chimica Ugo Schiff, Università di Firenze, Via della Lastruccia 3-13, I-50019 Sesto Fiorentino, Italy.
J Org Chem. 2013 Apr 5;78(7):3496-502. doi: 10.1021/jo400205j. Epub 2013 Mar 11.
A two-step one purification access to dichloronaphtho[1,2-b:8,7-b'] and [1,2-b:5,6-b']dithiophenes using bis-alkylnaphthyl alkynes and phthalimidesulfenyl chloride as starting materials has been developed. The functionalization of the carbon-chlorine bonds allowed further modification of NDT core, broadening the potential of the methodology.
采用双烷基萘基炔和邻苯二甲酰亚胺基二硫代氯化物作为起始原料，开发了一种两步一步纯化制备二氯萘并[1,2-b:8,7-b']和[1,2-b:5,6-b']二噻吩的方法。碳-氯键的功能化允许对 NDT 核心进行进一步修饰，拓宽了该方法的潜力。
