Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun, Jilin 130022, P. R. China.
Chem Soc Rev. 2013 Jun 21;42(12):5270-98. doi: 10.1039/c3cs35521g.
In the transition-metal-catalyzed cross-coupling reactions, the use of the first row transition metals as catalysts is much more appealing than the precious metals owing to the apparent advantages such as cheapness and earth abundance. Within the last two decades, particularly the last five years, explosive interests have been focused on the nickel-catalyzed Suzuki-Miyaura reactions. This has greatly advanced the chemistry of transition-metal-catalyzed cross-coupling reactions. Most notably, a broad range of aryl electrophiles such as phenols, aryl ethers, esters, carbonates, carbamates, sulfamates, phosphates, phosphoramides, phosphonium salts, and fluorides, as well as various alkyl electrophiles, which are conventionally challenging, by applying palladium catalysts can now be coupled efficiently with boron reagents in the presence of nickel catalysts. In this review, we would like to summarize the progress in this reaction.
在过渡金属催化交叉偶联反应中，由于廉价和丰富等明显优势，第一过渡金属作为催化剂的应用比贵金属更具吸引力。在过去的二十年中，特别是过去的五年中，人们对镍催化的 Suzuki-Miyaura 反应产生了浓厚的兴趣。这极大地推动了过渡金属催化交叉偶联反应的发展。值得注意的是，广泛的芳基亲电试剂，如酚类、芳基醚类、酯类、碳酸盐、氨基甲酸酯类、氨基磺酸酯类、磷酸盐、磷酰胺类、鏻盐和氟化物，以及各种烷基亲电试剂，以前用钯催化剂难以偶联，现在在镍催化剂的存在下可以与硼试剂有效地偶联。在这篇综述中，我们将总结该反应的进展。
