Optoelectronics Research Centre and Centre for Photonic Metamaterials, University of Southampton, Southampton SO17 1BJ, UK.
Nat Nanotechnol. 2013 Apr;8(4):252-5. doi: 10.1038/nnano.2013.25. Epub 2013 Mar 17.
Current efforts in metamaterials research focus on attaining dynamic functionalities such as tunability, switching and modulation of electromagnetic waves. To this end, various approaches have emerged, including embedded varactors, phase-change media, the use of liquid crystals, electrical modulation with graphene and superconductors, and carrier injection or depletion in semiconductor substrates. However, tuning, switching and modulating metamaterial properties in the visible and near-infrared range remain major technological challenges: indeed, the existing microelectromechanical solutions used for the sub-terahertz and terahertz regimes cannot be shrunk by two to three orders of magnitude to enter the optical spectral range. Here, we develop a new type of metamaterial operating in the optical part of the spectrum that is three orders of magnitude faster than previously reported electrically reconfigurable metamaterials. The metamaterial is actuated by electrostatic forces arising from the application of only a few volts to its nanoscale building blocks-the plasmonic metamolecules-that are supported by pairs of parallel strings cut from a flexible silicon nitride membrane of nanoscale thickness. These strings, of picogram mass, can be driven synchronously to megahertz frequencies to electromechanically reconfigure the metamolecules and dramatically change the transmission and reflection spectra of the metamaterial. The metamaterial's colossal electro-optical response (on the order of 10(-5)-10(-6) m V(-1)) allows for either fast continuous tuning of its optical properties (up to 8% optical signal modulation at up to megahertz rates) or high-contrast irreversible switching in a device only 100 nm thick, without the need for external polarizers and analysers.
当前,在超材料研究领域,人们主要致力于实现一些动态功能,如对电磁波的调控、切换和调制。为此,人们提出了多种方法,包括嵌入式变容二极管、相变材料、液晶的应用、利用石墨烯和超导体的电调制以及半导体衬底中的载流子注入或耗尽等。然而,在可见光和近红外波段内,对超材料属性进行调控、切换和调制仍然是重大的技术挑战:实际上,现有的用于亚太赫兹和太赫兹频段的微机电系统解决方案无法将尺寸缩小两个到三个数量级,从而进入光频带。在这里,我们开发了一种新型超材料,其工作在光谱的光学部分,其响应速度比以前报道的电可重构超材料快三个数量级。超材料通过施加几伏特的静电驱动力来驱动其纳米级结构单元——等离子体超分子,该超材料由从纳米级厚度的氮化硅薄膜上切下的一对平行弦支撑。这些质量为皮克克的弦可以以兆赫兹的频率同步驱动,从而机电地重新配置超分子,并显著改变超材料的透射和反射光谱。超材料的巨大电光响应(量级为 10(-5)-10(-6) m V(-1))可以实现其光学性能的快速连续调谐(高达 8%的光信号调制,调制频率高达兆赫兹),或者在厚度仅为 100nm 的器件中实现高对比度的不可逆切换,而无需外部起偏器和检偏器。