Division of Advanced Materials, Korea Research Institute of Chemical Technology, Yuseong-Gu, Daejeon, Korea.
Nano Lett. 2013 Apr 10;13(4):1764-9. doi: 10.1021/nl400349b. Epub 2013 Mar 21.
Chemically tuned inorganic-organic hybrid materials, based on CH3NH3(═MA)Pb(I(1-x)Br(x))3 perovskites, have been studied using UV-vis absorption and X-ray diffraction patterns and applied to nanostructured solar cells. The band gap engineering brought about by the chemical management of MAPb(I(1-x)Br(x))3 perovskites can be controllably tuned to cover almost the entire visible spectrum, enabling the realization of colorful solar cells. We demonstrate highly efficient solar cells exhibiting 12.3% in a power conversion efficiency of under standard AM 1.5, for the most efficient device, as a result of tunable composition for the light harvester in conjunction with a mesoporous TiO2 film and a hole conducting polymer. We believe that the works highlighted in this paper represent one step toward the realization of low-cost, high-efficiency, and long-term stability with colorful solar cells.
基于 CH3NH3(═MA)Pb(I(1-x)Br(x))3 钙钛矿的化学调控无机-有机杂化材料,通过紫外-可见吸收和 X 射线衍射图谱进行了研究,并应用于纳米结构太阳能电池。通过对 MAPb(I(1-x)Br(x))3 钙钛矿的化学管理进行能带隙工程,可以对其进行可控调节,以覆盖几乎整个可见光谱,从而实现彩色太阳能电池。我们展示了高效的太阳能电池,在标准 AM 1.5 下的功率转换效率达到 12.3%,对于最有效的器件,由于可调谐的光收集器组成与介孔 TiO2 薄膜和空穴传输聚合物相结合,从而实现了这一结果。我们相信,本文中强调的工作代表了朝着实现低成本、高效率和长期稳定性的彩色太阳能电池迈出的一步。