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一种多样化的吲哚嗪和吲哚𬭩盐的通用方法。

A general method to diverse cinnolines and cinnolinium salts.

机构信息

Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, West China Medical School, Sichuan University, 29 Wangjiang Road, Chengdu 610064, PR China.

出版信息

Chemistry. 2013 May 10;19(20):6239-44. doi: 10.1002/chem.201300155. Epub 2013 Mar 28.

DOI:10.1002/chem.201300155
PMID:23553746
Abstract

Rhodium catalysis: A highly efficient and general method has been established to prepare cinnolines, cinnolinium salts, and polycyclic cinnolinium salts through the rhodium(III)-catalyzed oxidative C-H activation/cyclization of azo compounds with alkynes (see scheme). Key features of this methodology include the unprecedented capacity to create both cinnoline and cinnolinium frameworks.

摘要

铑催化

通过铑(III)催化的偶氮化合物与炔烃的氧化 C-H 活化/环化反应，建立了一种高效、通用的方法来制备吖啶、吖啶盐和多环吖啶盐（见方案）。该方法的关键特点包括前所未有的构建吖啶和吖啶鎓骨架的能力。

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A general method to diverse cinnolines and cinnolinium salts.一种多样化的吲哚嗪和吲哚𬭩盐的通用方法。
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Rhodium(III)-catalyzed synthesis of cinnolinium salts from azobenzenes and alkynes: application to the synthesis of indoles and cinnolines.铑(III)催化的由偶氮苯和炔烃合成的吖啶鎓盐：在吲哚和吖啶合成中的应用。
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引用本文的文献

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