在酚类反应伴侣存在下（对甲氧基苯基）（三氟甲基）重氮甲烷的光激活。
Photoactivation of (p-methoxyphenyl)(trifluoromethyl)diazirine in the presence of phenolic reaction partners.
机构信息
TU Braunschweig, Institute of Organic Chemistry, Hagenring 30, 38106 Braunschweig, Germany.
出版信息
Chemistry. 2013 May 17;19(21):6551-5. doi: 10.1002/chem.201203479. Epub 2013 Mar 28.
PMID:23553983
Abstract
Shine light on your chemistry! Irradiating 3-(4-methoxyphenyl)-3-(trifluoromethyl)-3H-diazirine in the presence of equimolar solutions of phenol and tyrosine derivatives leads to Friedel-Crafts alkylations (see scheme), which suggests a strategy for the development of "cleaner" diazirines for chemical biology.
摘要
揭示你的化学奥秘！在等摩尔苯酚和酪氨酸衍生物溶液的存在下辐照 3-(4-甲氧基苯基)-3-(三氟甲基)-3H-二氮烯，可导致傅-克烷基化反应（见方案），这为开发用于化学生物学的“更清洁”二氮烯提供了一种策略。
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