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电膜萃取——一种用于药物、化学、临床和环境分析的新型萃取技术。

Electromembrane extraction--a novel extraction technique for pharmaceutical, chemical, clinical and environmental analysis.

作者信息

Krishna Marothu Vamsi, Gorrepati Madhavi, Vusa Ramanasri

机构信息

Alliance Institute of Advanced Pharmaceutical and Health Sciences, Ameerpet, Hyderabad-500038, Andhra Pradesh, India.

出版信息

J Chromatogr Sci. 2013 Aug;51(7):619-31. doi: 10.1093/chromsci/bmt041. Epub 2013 Apr 17.

DOI:10.1093/chromsci/bmt041
PMID:23595685
Abstract

Electromembrane extraction (EME) is a novel sample preparation technique in pharmaceutical, chemical, clinical and environmental analysis. This technique uses electromigration across artificial liquid membranes for selective extraction of analytes and sample enrichment from complex matrices. This review focuses on the setup, general procedure and parameters affecting the extraction efficiency of EME. An overview of innovations in EME (on-chip EME, low voltage EME, drop-to-drop EME, pulsed EME and EME followed by low-density solvent based ultrasound-assisted emulsification microextraction) is also presented in this article and attention is focused on the use of EME for pharmaceutical, chemical, clinical and environmental analysis.

摘要

电膜萃取(EME)是一种应用于药物、化学、临床和环境分析领域的新型样品制备技术。该技术利用电迁移通过人工液膜,从复杂基质中选择性萃取分析物并实现样品富集。本文综述聚焦于电膜萃取的装置、一般流程以及影响萃取效率的参数。本文还概述了电膜萃取的创新进展(芯片上的电膜萃取、低电压电膜萃取、逐滴电膜萃取、脉冲电膜萃取以及电膜萃取结合基于低密度溶剂的超声辅助乳化微萃取),并重点关注电膜萃取在药物、化学、临床和环境分析中的应用。

相似文献

1
Electromembrane extraction--a novel extraction technique for pharmaceutical, chemical, clinical and environmental analysis.电膜萃取——一种用于药物、化学、临床和环境分析的新型萃取技术。
J Chromatogr Sci. 2013 Aug;51(7):619-31. doi: 10.1093/chromsci/bmt041. Epub 2013 Apr 17.
2
Low-voltage electrically-enhanced microextraction as a novel technique for simultaneous extraction of acidic and basic drugs from biological fluids.低压电增强微萃取作为一种从生物体液中同时提取酸性和碱性药物的新技术。
J Chromatogr A. 2012 Jun 22;1243:6-13. doi: 10.1016/j.chroma.2012.04.050. Epub 2012 Apr 26.
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Electro membrane extraction followed by low-density solvent based ultrasound-assisted emulsification microextraction combined with derivatization for determining chlorophenols and analysis by gas chromatography-mass spectrometry.电膜萃取结合基于低浓度溶剂的超声辅助乳化微萃取衍生化,用于测定氯酚类物质,并结合气相色谱-质谱法进行分析。
J Chromatogr A. 2012 Jun 22;1243:14-22. doi: 10.1016/j.chroma.2012.04.054. Epub 2012 May 1.
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Electromembrane extraction from aqueous samples containing polar organic solvents.从含有极性有机溶剂的水样中电渗析提取。
J Chromatogr A. 2013 Sep 20;1308:37-44. doi: 10.1016/j.chroma.2013.07.105. Epub 2013 Aug 6.
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Drop-to-drop microextraction across a supported liquid membrane by an electrical field under stagnant conditions.在停滞条件下通过电场在支撑液膜上进行逐滴微萃取。
J Chromatogr A. 2009 Feb 27;1216(9):1496-502. doi: 10.1016/j.chroma.2008.12.079. Epub 2008 Dec 30.
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Pulsed electromembrane extraction: a new concept of electrically enhanced extraction.脉冲电萃取:一种电增强萃取的新概念。
J Chromatogr A. 2012 Nov 2;1262:214-8. doi: 10.1016/j.chroma.2012.08.090. Epub 2012 Sep 3.
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Selective electromembrane extraction at low voltages based on analyte polarity and charge.基于分析物极性和电荷的低压选择性电膜萃取。
J Chromatogr A. 2012 Jul 27;1248:48-54. doi: 10.1016/j.chroma.2012.05.092. Epub 2012 Jun 5.
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Extraction of pyridine derivatives from human urine using electromembrane extraction coupled to dispersive liquid-liquid microextraction followed by gas chromatography determination.采用电膜萃取-分散液液微萃取联用技术从人尿中提取吡啶衍生物,并用气相色谱法进行测定。
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Kinetic aspects of hollow fiber liquid-phase microextraction and electromembrane extraction.中空纤维液相微萃取和电膜萃取的动力学方面。
Anal Chim Acta. 2012 Sep 12;742:10-6. doi: 10.1016/j.aca.2011.12.039. Epub 2011 Dec 27.
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Combination of Electromembrane Extraction and Liquid-Phase Microextraction in a Single Step: Simultaneous Group Separation of Acidic and Basic Drugs.一步法中电膜萃取与液相微萃取的结合:酸性和碱性药物的同时分组分离
Anal Chem. 2015 Jul 7;87(13):6951-7. doi: 10.1021/acs.analchem.5b01610. Epub 2015 Jun 15.

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Membranes (Basel). 2023 Jul 28;13(8):705. doi: 10.3390/membranes13080705.
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Trends in sample preparation and separation methods for the analysis of very polar and ionic compounds in environmental water and biota samples.环境水样和生物样品中非常极性和离子型化合物分析的样品前处理和分离方法的发展趋势。
Anal Bioanal Chem. 2020 Sep;412(24):6149-6165. doi: 10.1007/s00216-020-02811-5. Epub 2020 Jul 24.
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Hollow fiber-based liquid phase microextraction followed by analytical instrumental techniques for quantitative analysis of heavy metal ions and pharmaceuticals.
基于中空纤维的液相微萃取结合分析仪器技术用于重金属离子和药物的定量分析。
J Pharm Anal. 2020 Apr;10(2):109-122. doi: 10.1016/j.jpha.2019.12.003. Epub 2019 Dec 12.
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Quantitation of zolpidem in biological fluids by electro-driven microextraction combined with HPLC-UV analysis.通过电动微萃取结合高效液相色谱-紫外分析法定量生物流体中的唑吡坦。
EXCLI J. 2018 Apr 23;17:349-361. doi: 10.17179/excli2018-1140. eCollection 2018.
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Electromembrane extraction-Recent trends and where to go.电膜萃取——最新趋势与发展方向
J Pharm Anal. 2017 Jun;7(3):141-147. doi: 10.1016/j.jpha.2017.04.002. Epub 2017 Apr 12.
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Electroextraction and electromembrane extraction: Advances in hyphenation to analytical techniques.电萃取和电膜萃取:与分析技术联用的进展
Electrophoresis. 2016 May;37(9):1170-86. doi: 10.1002/elps.201500530. Epub 2016 Mar 31.