University of Cambridge, Department of Chemistry, Lensfield Road, Cambridge CB2 1EW, UK.
Angew Chem Int Ed Engl. 2013 May 27;52(22):5749-52. doi: 10.1002/anie.201209708. Epub 2013 Apr 18.
: A dynamic combinatorial library of polycatenated tetrahedra was prepared by complexation between a dynamic FeL tetrahedral cage, constructed from ligands containing an electron‐deficient naphthalenediimide core, and an electron‐rich aromatic crown ether, 1,5‐dinaphtho[38]crown‐10. The highest order species in the library is the tetrahedral [7]catenane.[Image: see text]
: 一种多轮烷四面体的动态组合库是通过一个动态的 FeL 四面体笼与一个富电子的芳香冠醚 1,5-二萘并[38]冠-10 之间的络合作用制备的,该四面体笼由含有缺电子萘二酰亚胺核心的配体构建而成。库中最高阶的物种是四面体[7]轮烷。[图像:见正文]