单电子转移诱导的烯基卤化物与芳基格氏试剂的交叉偶联反应。
Single electron transfer-induced cross-coupling reaction of alkenyl halides with aryl Grignard reagents.
机构信息
Department of Chemistry, Graduate School of Science, Kyoto University, Kyoto 606-8502, Japan.
出版信息
Chem Commun (Camb). 2013 Jun 7;49(45):5219-21. doi: 10.1039/c3cc41923a.
PMID:23628923
Abstract
Alkenyl halides were found to undergo coupling with aryl Grignard reagents to give the corresponding styrene derivatives in a stereo-retained manner. The cross-coupling reaction is considered to proceed through a single electron transfer mechanism.
摘要
烯基卤化物被发现与芳基格氏试剂发生偶联反应，以立体保留的方式生成相应的苯乙烯衍生物。交叉偶联反应被认为是通过单电子转移机制进行的。
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