Xi Hongzhu, Liu Qian, Tian Ye, Guo Shengming, Cu Maoyou, Zhang Gengmin
National Center for Nanoscience and Technology, China, Beijing 100080, China.
J Nanosci Nanotechnol. 2013 Feb;13(2):829-33. doi: 10.1166/jnn.2013.5969.
Ge1.5Sn0.5Sb2Te5 (GSST) can be easily induced to phase transition from amorphous state to crystalline state by a laser direct writing (LDW) system. The results show that the crystalline phase of GSST is more durable against acid solution corrosion than the amorphous phase. So nano-scale patterns and structures can be formed on the GSST film resists using laser-induced phase change and wet etching. Moreover, reactive ion etching (RIE) technology was applied to transfer these patterns onto the SiO2 substrate. The result shows to the extent that GSST material has thermal resist characteristics with high resolution and well etching selectivity to SiO2 when etched in the CHF3, which is compatibility with the future nanofabricate processing.
Ge1.5Sn0.5Sb2Te5(GSST)可通过激光直写(LDW)系统轻松诱导从非晶态转变为晶态。结果表明,GSST的晶相比非晶相对酸性溶液腐蚀更具耐久性。因此,利用激光诱导相变和湿法蚀刻可在GSST薄膜抗蚀剂上形成纳米级图案和结构。此外,采用反应离子蚀刻(RIE)技术将这些图案转移到SiO2衬底上。结果表明,GSST材料在CHF3中蚀刻时具有热阻特性,对SiO2具有高分辨率和良好的蚀刻选择性,这与未来的纳米制造工艺兼容。