Dipartimento di Fisica, Universitá di Roma La Sapienza, I-00185, Roma, Italy.
Nat Commun. 2013;4:1793. doi: 10.1038/ncomms2826.
The lack of long-range structural order in amorphous solids induces well known thermodynamic anomalies, which are the manifestation of distinct peculiarities in the vibrational spectrum. Although the impact of such anomalies vanishes in the long wavelength, elastic continuum limit, it dominates at length scales comparable to interatomic distances, implying an intermediate transition regime still poorly understood. Here we report a study of such mesoscopic domains by means of a broadband version of picosecond photo-acoustics, developed to coherently generate and detect hypersonic sound waves in the sub-THz region with unprecedented sampling efficiency. We identify a temperature-dependent fractal v(3/2) frequency behaviour of the sound attenuation, pointing to the presence of marginally stable regions and a transition between the two above mentioned limits. The essential features of this behaviour are captured by a theoretical approach based on random spatial variation of the shear modulus, including anharmonic interactions.
非晶态固体中缺乏长程结构有序性会导致众所周知的热力学异常,这些异常是振动谱中明显特征的表现。尽管这些异常在长波长、弹性连续体极限下消失,但在与原子间距离相当的尺度上,它们占据主导地位,这意味着中间过渡态仍未被充分理解。在这里,我们通过一种超宽带的皮秒光声技术研究了这种介观区域,该技术发展用于以亚太赫兹区域前所未有的采样效率相干地产生和检测超声速声波。我们发现,在亚太赫兹区域,声衰减的 v(3/2)频率随温度的变化呈分形行为,这表明存在边缘稳定区域和上述两种极限之间的转变。这种行为的基本特征被一种基于剪切模量随机空间变化的理论方法所捕捉,该方法包括非谐相互作用。