铜介导的烯丙基锆烯与 O-苯甲酰基酮肟和醛肟的亲电亚胺化反应。
Copper-mediated electrophilic imination of alkenylzirconocenes with O-benzoyl ketoximes and aldoximes.
机构信息
Institute of Chemistry and Chemical Engineering, Hebei Normal University, Shijiazhuang 050091, China.
出版信息
Chem Commun (Camb). 2013 Jun 18;49(48):5513-5. doi: 10.1039/c3cc41574k. Epub 2013 May 10.
PMID:23660950
Abstract
Copper-mediated electrophilic imination of alkenylzirconocenes generated in situ from alkynes and zirconocenes is accomplished under mild reaction conditions. The reaction can be used to prepare various 2-azadienes.
摘要
铜介导的烯丙基锆烯原位生成的亲电亚胺化反应在温和的反应条件下完成。该反应可用于制备各种 2-氮杂二烯。
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