铜介导的烯丙基锆烯与酰基叠氮化物的酰胺化反应：烯酰胺的形成。
Copper-mediated amidation of alkenylzirconocenes with acyl azides: formation of enamides.
机构信息
Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University , Beijing 100084, China , and Institute of Chemistry and Chemical Engineering, Hebei Normal University , Shijiazhuang 050091, China.
出版信息
Org Lett. 2013 Oct 18;15(20):5174-7. doi: 10.1021/ol402212g. Epub 2013 Oct 1.
PMID:24083640
Abstract
Copper-mediated amidation of alkenylzirconocenes generated in situ from alkynes and zirconocenes with acyl azides is accomplished under mild conditions. The reaction can be used to prepare various enamides.
摘要
铜介导的酰胺化反应，是由炔烃和锆烯原位生成的烯基锆烯与酰基叠氮化物在温和条件下完成的。该反应可用于制备各种烯酰胺。
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