Department of Chemical Engineering, University of New Brunswick, Fredericton, NB, Canada E3B 5A3.
Mar Pollut Bull. 2013 Jul 15;72(1):205-12. doi: 10.1016/j.marpolbul.2013.03.042. Epub 2013 May 9.
The increasing risks of potential oil spills in the arctic regions, which are characterized by low temperatures, are a big challenge. The traditional dispersant method has shown limited effectiveness in oil cleanup. This work studied the role of mineral fines in the formation of oil-mineral aggregates (OMAs) at low temperature (0-4 °C) environment. The loading amount of minerals and dispersant with different dispersant and oil types were investigated under a full factorial design. The shapes and sizes of OMAs were analyzed. Results showed that the behavior of OMA formation differs when dispersant and mineral fines are used individually or together. Both the experimental and microscopic results also showed the existence of optimal dispersant to oil ratios and mineral to oil ratios. In general, poor oil removal performance was observed for more viscous oil. Corexit 9500 performed better than Corexit 9527 with various oils, in terms of oil dispersion and OMA formation.
北极地区的石油泄漏风险日益增加,其特点是低温。传统的分散剂方法在清除石油方面效果有限。本工作研究了在低温(0-4°C)环境下,矿物细粉在油-矿物聚集体(OMA)形成中的作用。采用完全析因设计,研究了不同分散剂和油类的矿物加载量和分散剂用量。分析了 OMA 的形状和尺寸。结果表明,单独使用分散剂和矿物细粉或一起使用时,OMA 形成的行为不同。实验和微观结果还表明,存在最佳的分散剂与油比和矿物与油比。一般来说,对于粘性较大的油,去除油的性能较差。对于各种油,Corexit 9500 的油分散和 OMA 形成性能均优于 Corexit 9527。