Chemistry and Physics of Materials Unit and CSIR Centre of Excellence in Chemistry, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur P.O., Bangalore 560 064, India.
Chemphyschem. 2001 Feb 16;2(2):78-105. doi: 10.1002/1439-7641(20010216)2:2<78::AID-CPHC78>3.0.CO;2-7.
Carbon nanotubes were discovered soon after the successful laboratory synthesis of fullerenes. Since their discovery in 1991, there has been intensive research activity in the area of carbon nanotubes, not only because of their fascinating structural features and properties, but also because of their potential technological applications. There is increasing experimental evidence to show that carbon nanotubes may find use in nanoelectronic devices, displays, and in hydrogen storage. In this article, we discuss various important aspects related to the synthesis, structure, characterization, and mechanism of formation of multi-walled and single-walled carbon nanotubes, followed by a presentation of the important electronic, mechanical, hydrogen storage, and other properties of the nanotubes. Doping, as well as other chemical manipulations with boron and nitrogen, bring about significant changes in the properties of the nanotubes. Carbon nanotubes also serve as useful templates to make other nanostructures. Layered metal chalcogenides, boron nitride, and other materials form nanotubes and provide considerable scope for study.
碳纳米管是在富勒烯的实验室成功合成后不久被发现的。自 1991 年被发现以来,碳纳米管领域的研究活动十分活跃,这不仅是因为它们引人入胜的结构特征和性能,还因为它们具有潜在的技术应用。越来越多的实验证据表明,碳纳米管可能在纳米电子器件、显示器和储氢方面得到应用。在本文中,我们将讨论与多壁和单壁碳纳米管的合成、结构、表征和形成机制相关的各种重要方面,接着介绍纳米管的重要电子、机械、储氢和其他性质。掺杂以及硼和氮的其他化学处理会导致纳米管性质的显著变化。碳纳米管还可用作制备其他纳米结构的有用模板。层状金属硫属化物、氮化硼和其他材料形成纳米管,为研究提供了很大的空间。