通过铜（I）催化的偕-选择性 1,3-偶极环加成反应，不对称构建氟化咪唑烷：亚胺叶立德与氟化亚胺的反应。
Asymmetric construction of fluorinated imidazolidines via Cu(I)-catalyzed exo'-selective 1,3-dipolar cycloaddition of azomethine ylides with fluorinated imines.
机构信息
College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China.
出版信息
Chem Commun (Camb). 2013 Jul 18;49(56):6277-9. doi: 10.1039/c3cc43025a.
PMID:23736846
Abstract
Expedient access to optically active fluorinated 2,4-trans-imidazolidines was successfully developed via Cu(I)-catalyzed exo'-selective 1,3-DC of azomethine ylides with fluorinated imines.
摘要
通过铜（I）催化的偕氮丙啶与氟代亚胺的外选择性 1,3-DC，成功开发了一种获得光学活性氟化 2,4-反式-咪唑烷的便捷方法。
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