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纳米级无机成分对模型复合材料光学和表面性质的影响。

The influence of nanoscale inorganic content over optical and surface properties of model composites.

作者信息

Salgado Vinícius Esteves, Cavalcante Larissa Maria, Silikas Nick, Schneider Luis Felipe J

机构信息

School of Dentistry, Federal Fluminense University, Niterói, Brazil.

出版信息

J Dent. 2013 Nov;41 Suppl 5:e45-53. doi: 10.1016/j.jdent.2013.05.011. Epub 2013 Jun 6.

Abstract

OBJECTIVES

To investigate the influence of nanoscale inorganic content over optical and surface properties of model composites before and after ageing.

METHODS

Three model composites were formulated with silica fillers in nanoscale of 7 nm (G1), 12 nm (G2) and 16 nm (G3), at 45.5% by weight in a matrix of BisGMA/TEGDMA 1:1. Color coordinates (CIE Lab* parameters), color difference (ΔE*), translucency parameter (TP), surface gloss (SG) and surface roughness (SR) were measured before and after ageing procedures of immersion in water and toothbrush abrasion. Surface hardness (SH) were evaluated before and after immersion in absolute ethanol. Results were submitted to two-way ANOVA followed by Tukey's post hoc test performed at a pre-set alpha of 0.05.

RESULTS

Regarding CIE Lab* parameters, a darkening, a redness and a blueness effect, were respectively detected after water storage for all groups. Smaller filler sizes (G1) had the highest CIE b* values, whereas medium (G2) (p<0.05) had higher values than larger fillers (G3) (p<0.05) either before or after water immersion. Toothbrush abrasion did not produce any significant effect on CIE a* and CIE b* values, however increased CIE L*, decreased TP in addition to produce rougher and matte surfaces in all groups. Filler size did not influence ΔE* (p>0.05), although a tendency towards lower values in smaller filler materials was observed. Ageing after immersion in absolute ethanol decreased SH for all model composites.

CONCLUSIONS

Filler sizes and ageing procedures influenced the optical and surface properties of the nanostructured composites evaluated in this study.

CLINICAL SIGNIFICANCE

Filler size influenced optical and surface properties of resin composites. Materials containing smaller filler size offered improved optical stability and surface properties that can lead to longer maintenance of the restoration's appearance in the oral environment.

摘要

目的

研究纳米级无机成分对模型复合材料老化前后光学性能和表面性能的影响。

方法

制备三种模型复合材料,分别含有7nm(G1)、12nm(G2)和16nm(G3)的纳米级二氧化硅填料,在BisGMA/TEGDMA 1:1的基质中重量占比为45.5%。在水浸和牙刷磨损的老化程序前后,测量颜色坐标(CIE Lab参数)、色差(ΔE)、半透明参数(TP)、表面光泽度(SG)和表面粗糙度(SR)。在绝对乙醇中浸泡前后评估表面硬度(SH)。结果进行双向方差分析,随后进行Tukey事后检验,预设α为0.05。

结果

关于CIE Lab参数,所有组在水储存后分别检测到变暗、变红和变蓝的效果。较小的填料尺寸(G1)具有最高的CIE b值,而中等尺寸(G2)(p<0.05)在水浸前后的值均高于较大填料尺寸(G3)(p<0.05)。牙刷磨损对CIE a*和CIE b*值没有产生任何显著影响,但增加了CIE L*,降低了TP,此外还使所有组的表面更粗糙且呈哑光状。填料尺寸对ΔE*没有影响(p>0.05),尽管观察到较小填料材料的值有降低的趋势。在绝对乙醇中浸泡后的老化降低了所有模型复合材料的SH。

结论

填料尺寸和老化程序影响了本研究中评估的纳米结构复合材料的光学和表面性能。

临床意义

填料尺寸影响树脂复合材料的光学和表面性能。含有较小填料尺寸的材料具有更好的光学稳定性和表面性能,这可以使修复体在口腔环境中的外观维持更长时间。

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