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为了使铁（II）配合物的金属到配体电荷转移态具有更长的寿命：一种 N-杂环卡宾的方法。

Towards longer-lived metal-to-ligand charge transfer states of iron(II) complexes: an N-heterocyclic carbene approach.

机构信息

Centre for Analysis and Synthesis, Department of Chemistry, Lund University, Box 124, 22100 Lund, Sweden.

出版信息

Chem Commun (Camb). 2013 Jul 21;49(57):6412-4. doi: 10.1039/c3cc43833c.

DOI:10.1039/c3cc43833c
PMID:23752944
Abstract

A 9 ps (3)MLCT lifetime was achieved by a Fe(II) complex based on C(NHC)^N(py)^C(NHC) pincer ligands. This is the longest known so far for any kind of complexes of this abundant metal, and increased by almost two orders of magnitude compared to the reference Fe(II) bis-terpyridine complex.

摘要

基于 C(NHC)^N(py)^C(NHC) 钳形配体的 Fe(II) 配合物实现了 9 ps (3)MLCT 寿命。这是目前为止已知的任何此类丰富金属配合物中最长的寿命，与参考的 Fe(II) 双-联吡啶配合物相比，增加了近两个数量级。

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