铑(III)催化的 C-H 烯丙基化反应用于使用氧化导向基团合成邻烯基苯酚。
Rhodium(III)-catalyzed C-H olefination for the synthesis of ortho-alkenyl phenols using an oxidizing directing group.
机构信息
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China.
出版信息
Org Lett. 2013 Jul 5;15(13):3366-9. doi: 10.1021/ol4014188. Epub 2013 Jun 20.
PMID:23786398
Abstract
By using an oxidizing directing group, a mild, efficient Rh(III) catalyzed C-H olefination reaction between N-phenoxyacetamides and alkenes was developed. This reaction provided a straightforward way for the synthesis of ortho-alkenyl phenols, and the directing group is traceless in the product.
摘要
通过使用一个氧化导向基团，开发了一种温和、高效的 Rh(III)催化 N-苯氧基乙酰胺和烯烃之间的 C-H 烯丙基化反应。该反应为邻位烯基苯酚的合成提供了一种直接的方法，并且导向基团在产物中是无痕的。
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