State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China.
Org Lett. 2013 Jul 5;15(13):3366-9. doi: 10.1021/ol4014188. Epub 2013 Jun 20.
By using an oxidizing directing group, a mild, efficient Rh(III) catalyzed C-H olefination reaction between N-phenoxyacetamides and alkenes was developed. This reaction provided a straightforward way for the synthesis of ortho-alkenyl phenols, and the directing group is traceless in the product.
通过使用一个氧化导向基团，开发了一种温和、高效的 Rh(III)催化 N-苯氧基乙酰胺和烯烃之间的 C-H 烯丙基化反应。该反应为邻位烯基苯酚的合成提供了一种直接的方法，并且导向基团在产物中是无痕的。
