Energy and Semiconductor Research Laboratory, Department of Physics, University of Oldenburg, Carl-von-Ossietzky Str. 9-11, 26129 Oldenburg, Germany.
Chemistry. 2013 Jul 22;19(30):9746-53. doi: 10.1002/chem.201301076. Epub 2013 Jun 20.
Ternary semiconductor nanocrystals, such as CuInSe2 , are of high interest for photovoltaic application due to their relatively low toxicity and unique properties. During the last decades great success has been achieved in the colloidal synthesis of binary nanoparticles, but for ternary compounds this research is still in an early stage of development. These materials are a challenge for synthetic chemistry, because the interaction between the three components (copper, indium, and selenium) plays a major role for the production of high quality material. The purpose of this Minireview is to provide a summary of the achievements in colloidal synthesis of CuInSe2 nanoparticles--in particular, details of reaction mechanism and its characterization possibilities, which might be useful also for the colloidal synthesis of other multicomponent systems.
三元半导体纳米晶体,如 CuInSe2,由于其相对较低的毒性和独特的性质,在光伏应用中受到高度关注。在过去的几十年中,二元纳米粒子的胶体合成取得了巨大的成功,但对于三元化合物,这项研究仍处于早期发展阶段。这些材料对合成化学来说是一个挑战,因为三种成分(铜、铟和硒)之间的相互作用对于生产高质量的材料起着重要作用。本文综述的目的是提供胶体合成 CuInSe2 纳米粒子方面的成就的总结,特别是反应机制的细节及其可能的特性,这对于胶体合成其他多组分体系也可能是有用的。