链状聚[[(三苯基膦-κP)银(I)]-μ-4,4'-联吡啶-κ(2)N:N'-[(三苯基膦-κP)银(I)]-二-μ-氯化物]
catena-Poly[[(tri-phenyl-phosphane-κP)silver(I)]-μ-4,4'-bi-pyridine-κ(2) N:N'-[(tri-phenyl-phosphane-κP)silver(I)]-di-μ-chlorido].
作者信息
Song Xiao-Ming, Hu Feng, Shi Hua-Tian, Chen Qun, Zhang Qian-Feng
机构信息
Department of Applied Chemistry, School of Petrochemical Engineering, Changzhou University, Jiangsu 213164, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2013 May 25;69(Pt 6):m342. doi: 10.1107/S160053681301413X. Print 2013 Jun 1.
In the title coordination polymer, [Ag2Cl2(C10H8N2)(C18H15P)2] n , the Ag(I) cation is coordinated by a 4,4'-bi-pyridine N atom, a tri-phenyl-phosphane P atom and two Cl(-) anions in a distorted tetra-hedral geometry. The 4,4-bi-pyridine and Cl(-) anions bridge the Ag(I) cations, forming polymeric chains running along [21-1]. In the crystal, weak C-H⋯Cl inter-actions link the polymeric chains into a three-dimensiona supra-molecular architecture.
在标题配位聚合物[Ag2Cl2(C10H8N2)(C18H15P)2]n中，Ag(I)阳离子由一个4,4'-联吡啶N原子、一个三苯基膦P原子和两个Cl(-)阴离子以扭曲的四面体几何构型配位。4,4-联吡啶和Cl(-)阴离子桥连Ag(I)阳离子，形成沿[21-1]方向延伸的聚合物链。在晶体中，弱的C-H⋯Cl相互作用将聚合物链连接成三维超分子结构。
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