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2-（4-溴苯基）-4-（4-甲氧基苯基）-6,7,8,9-四氢-5H-环庚并[b]吡啶

2-(4-Bromo-phen-yl)-4-(4-meth-oxy-phen-yl)-6,7,8,9-tetra-hydro-5H-cyclo-hepta-[b]pyridine.

作者信息

Celik Ismail, Akkurt Mehmet, Gezegen Hayreddin, Kazak Canan

机构信息

Department of Physics, Faculty of Sciences, Cumhuriyet University, 58140 Sivas, Turkey.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 May 25;69(Pt 6):o956. doi: 10.1107/S1600536813013913. Print 2013 Jun 1.

DOI:10.1107/S1600536813013913
PMID:23795115
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3685096/
Abstract

In the title compound, C23H22BrNO, the cyclo-heptane ring adopts a chair conformation. The pyridine ring makes dihedral angles of 58.63 (15) and 8.27 (16)° with the benzene rings. The dihedral angle between the benzene rings is 56.68 (17)°. The crystal packing features C-Br⋯π inter-actions [Br⋯centroid distances= 3.813 (2) and 3.839 (2) Å; C-Br⋯centroid = 126.25 (10) and 138.31 (10)°, respectively, forming a three dimensional supramolecular architecture.

摘要

在标题化合物C₂₃H₂₂BrNO中，环庚烷环呈椅式构象。吡啶环与苯环的二面角分别为58.63 (15)°和8.27 (16)°。苯环之间的二面角为56.68 (17)°。晶体堆积具有C-Br⋯π相互作用[Br⋯质心距离 = 3.813 (2) 和3.839 (2) Å；C-Br⋯质心分别为126.25 (10)°和138.31 (10)°]，形成三维超分子结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e2d/3685096/92b0efe6cfa6/e-69-0o956-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e2d/3685096/95382312a73a/e-69-0o956-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e2d/3685096/92b0efe6cfa6/e-69-0o956-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e2d/3685096/95382312a73a/e-69-0o956-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e2d/3685096/92b0efe6cfa6/e-69-0o956-fig2.jpg

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