通过 Pd(II) 催化实现膦酸和磷酸单酸的邻乙酰氧基化。
ortho-Acetoxylation of phosphonic and phosphoric monoacids via Pd(II) catalysis.
机构信息
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore.
出版信息
J Org Chem. 2013 Sep 6;78(17):8826-32. doi: 10.1021/jo4011188. Epub 2013 Aug 16.
PMID:23915334
Abstract
A simple and efficient method is developed for Pd-catalyzed ortho-acetoxylation using organophosphates, namely, benzylic phosphonic and aryl phosphoric monoacids, as the directing group.
摘要
开发了一种简单高效的 Pd 催化邻位乙酰氧基化方法，使用有机磷酸酯，即苄基膦酸和芳基磷酸单酸，作为导向基团。
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