Department of Chemistry, Department of Materials Science and Engineering, Institute for NanoBioTechnology, Johns Hopkins University, Baltimore, MD 21218, USA.
Macromol Rapid Commun. 2013 Sep;34(17):1343-50. doi: 10.1002/marc.201300423. Epub 2013 Aug 6.
Polydiacetylenes have received intense attention on account of their well-established chromic alterations that are detectable often by the naked eye, making them ideal for a variety of applications such as biosensory materials. These polymers have been fabricated in a variety of materials platforms including 3D crystals, 2D monolayers, and 0D spherical vesicles; however, 1D morphologies that might be useful for directional energy migration are less common. This article describes the development and current research efforts of protein-based 1D nanowire-like supramolecular assemblies with embedded polydiacetylenes.
聚二乙酰烯因其稳定的显色变化而备受关注,这些显色变化通常可以用肉眼检测到,这使得它们成为各种应用的理想选择,如生物感应材料。这些聚合物已经在多种材料平台上进行了制备,包括 3D 晶体、2D 单层和 0D 球形囊泡;然而,对于定向能量迁移可能有用的 1D 形态则较少见。本文描述了基于蛋白质的具有嵌入式聚二乙酰烯的 1D 纳米线状超分子组装体的开发和当前研究进展。