School of Chemistry and Chemical Technology and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China.
Chem Commun (Camb). 2013 Sep 25;49(74):8253-5. doi: 10.1039/c3cc43549k.
A chiral porous metal-organic framework of an axially C2-symmetric 1,1'-biphenol ligand is constructed and can be used as a solid-state host to enanioselectively adsorb mandelates with up to 93.1% ee and to entrap achiral tropolone ethers and induce their asymmetric photocyclization with up to 98.5% ee.
构建了一个轴向 C2 对称的 1,1'-联苯酚配体的手性多孔金属有机骨架，可作为固态主体，对扁桃酸盐进行对映选择性吸附，ee 值最高可达 93.1%，并包合物化非手性的三羟甲基噁唑烷酮醚，诱导其不对称光环化，ee 值最高可达 98.5%。
