College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, Jiangsu, P. R. China.
Chem Commun (Camb). 2013 Oct 18;49(81):9248-50. doi: 10.1039/c3cc45066j.
Ambient temperature solid-state reaction of Pb(OAc)2 with TabHPF6 afforded an intermediate product [Pb(Tab)2]2(PF6)4, which further reacted with 4,4'-bipy in the solid state to generate a unique 2D cationic coordination polymer Pb(Tab)2(4,4'-bipy)2 in quantitative yield. Both complexes possess a low dielectric constant and low dielectric loss in the high electric field frequency range.
室温下，Pb(OAc)2 与 TabHPF6 发生固相反应，生成中间体 [Pb(Tab)2]2(PF6)4，后者与 4,4'-bipy 在固态下进一步反应，生成具有独特二维阳离子配位聚合物 Pb(Tab)2(4,4'-bipy)2，产率为定量。这两种配合物在高电场频率范围内具有低介电常数和低介电损耗。
